Resulting from its irregular spherical morphology with out any indication of a core-shell structure irregular spherical morphology with out any indication of a coreshell structure as a consequence of its prepared hydrophobicity and poor reaction with acrylate monomers. As for the composites hydrophobicity and poor reaction with acrylate monomers. As for the composites pre due to in the modified epoxy resins, they show a spherical structure (Figure 5b,c) pared from the modified epoxy resins, they show a spherical structure (Figure 5b,c) be core-shell their facile reaction together with the acrylate monomer. Nonetheless, the three-layer reason for their facile reaction together with the acrylate monomer. Nonetheless, the 4′-Methoxyflavonol site threelayer core monomer structure was not observable (Figure 5c), plausibly owing for the similarity of your composition amongst the intermediate layer and shell layer.Coatings 2021, 11, x FOR PEER REVIEWCoatings 2021, 11, x FOR PEER REVIEW9 of9 ofCoatings 2021, 11,shell structure was not observable (Figure 5c), plausibly owing for the similarity of your monomer composition in between the intermediate layer and shell layer. for the similarity with the shell structure was not observable (Figure 5c), plausibly owingmonomer composition between the intermediate layer and shell layer.9 ofFigure five. TEM of (a) E44, and that of waterborne epoxystyrene crylate composites with (b) con Figure five. TEM of (a) E-44, and that of waterborne epoxy-styrene crylate composites with (b) Figure five. TEM of (a) E44, and that of waterborne epoxystyrene crylate composites with (b) con ventional core hell structure and (c) threelayer core hell structure. conventional core-shell structure and (c) three-layer core-shell structure. ventional core hell structure and (c) threelayer core hell structure.three.4. Determination of Intermediate Layer Hesperidin Epigenetic Reader Domain thickness of Three-Layer Core-Shell Emulsion 3.4. Determination of Intermediate Layer Thickness of ThreeLayer Core hell Emulsion three.4. Determination of Intermediate Layer Thickness of ThreeLayer Core hell Emulsion To identify thermal events, a DSC test was carried out (Figure 6a). To identify thermal events, a DSC test was conducted (Figure 6a). To recognize thermal events, a DSC test was carried out (Figure 6a).Figure six. DSC curves and TOPEM-DSC curves of waterborne epoxy-styrene crylate composite emulsion film: (a) DSC curves; TOPEM-DSC curves of (b) three-layer core-shell structure and (c) traditional core-shell structure. (15 modified E-44, the whole: entire latex particle, core: pure core polymer, and shell: pure shell polymer).Coatings 2021, 11,ten ofThere are three glass transitions for the three-layer core-shell composite, whereas you can find only two glass transitions for the conventional core-shell emulsion film. A far more detailed structure characterization of your three-layer core-shell emulsion film was conducted by TOPEM-DSC (Figure 6b). For comparison, the traditional core-shell emulsion film was also characterized (Figure 6c). Determined by the TOPEM-DSC curves, the precise heat capacity C_p of each phase of the film within the quasi-steady state may be obtained. The mass fraction of every phase can then be calculated by utilizing the formula, as well as the thickness of each and every layer of the latex particles can be calculated by combining using the particle size outcomes, as shown in Table two. As can be observed, the sum of c and s for the standard core-shell particle is much less than 1, indicating the existence of an interface layer Ri. As a result of the similarity in the monomer compos.
